For two particle system, the position vector of centre of mass of the two particle system is given by,
$$\vec{r} = \frac {m_1 \vec{r_1} + m_2 \vec{r_2}}{m_1+m_2}$$
For two particle system, velocity of centre of mass is given by,
$$\vec{v_c} = \frac {m_1 \vec{v_1} + m_2 \vec{v_2}}{m_1+m_2}$$
Whewe,
\(m_1\) and \(m_2\) are the masses of two particles.
\(\vec{r_1}\) and \(\vec{r_2}\) are the position vector of the particles \(m_1\) and \(m_2\) respectively.
\(\vec{v_1}\) and \(\vec{v_2}\) are velocities of the particles \(m_1\) and \(m_2\) respectively.